Don't do the cloroform thing. In the movies chloroform works with just a few drops and only gives the person a headache, but if you actually put enough in real life to get them to pass out you'd probably kill them :)
I think its best to do a combination of things. Go up to her and introduce yourself. Start a conversation, be confident but not cocky, talk but don't make it all about you. Let the woman to most of the talking actually, thats the best thing. Don't be distant, but don't be too forthcoming.
I think a good conversation is the key though, flash a smile and if she smiles back thats a good sign.
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